(Cyanido-kappa C)(2,2-diphenylacetamido-kappa N-2,O)bis(g5-pentamethylcyclopenta-dienyl) zirconium(IV)

被引：2
|
作者：
Becker, Lisanne [1 ]
Spannenberg, Anke [1 ]
Arndt, Perdita [1 ]
Rosenthal, Uwe [1 ]
机构：
[1] Katalyse eV Univ Rostock, Leibniz Inst, Albert Einstein Str 29A, D-18059 Rostock, Germany
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2014年 / 70卷
关键词：
data-to-parameter ratio = 17.9; mean σ(C-C) = 0.003 Å; R factor = 0.033; single-crystal X-ray study; T = 150 K; wR factor = 0.085;
D O I：
10.1107/S1600536814001160
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, [Zr(C10H15)(2)(C14H12NO)(CN)], the Zr-IV atom is coordinated by two pentamethylcyclopentadienyl ligands, the amidate ligand via the N and O atoms, and an additional C N ligand. The four-membered metallacycle is nearly planar (r.m.s. deviation = 0.008 angstrom). In the crystal, the molecules are connected into centrosymmetric dimers via pairs of N-H center dot center dot center dot N hydrogen bonds.
引用
收藏
页码：M57 / +
页数：10
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