STEREOSPECIFIC TOTAL SYNTHESIS AND ABSOLUTE-CONFIGURATION OF (+)-METHYLENOMYCIN-A

被引：37
作者：
JERNOW, J
TAUTZ, W
ROSEN, P
BLOUNT, JF
机构：
[1] Chemical Research Department, Hoffmann-La Roche Inc., Nutley
来源：
JOURNAL OF ORGANIC CHEMISTRY | 1979年 / 44卷 / 23期
关键词：
D O I：
10.1021/jo01337a048
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Starting from 2,3-dimethyl-l-oxocyclopent-2-ene-4-carboxylic acid (4), a stereospecific synthesis of (+)-methylenomycin A (1) was accomplished and its absolute configuration was determined via X-ray crystallo-graphic techniques. © 1979, American Chemical Society. All rights reserved.
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页码：4210 / 4212
页数：3
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