STEREOSPECIFIC TOTAL SYNTHESIS AND ABSOLUTE-CONFIGURATION OF (+)-METHYLENOMYCIN-A

被引：38

作者：

JERNOW, J

TAUTZ, W

ROSEN, P

BLOUNT, JF

机构：

[1] Chemical Research Department, Hoffmann-La Roche Inc., Nutley

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1979年 / 44卷 / 23期

关键词：

D O I：

10.1021/jo01337a048

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Starting from 2,3-dimethyl-l-oxocyclopent-2-ene-4-carboxylic acid (4), a stereospecific synthesis of (+)-methylenomycin A (1) was accomplished and its absolute configuration was determined via X-ray crystallo-graphic techniques. © 1979, American Chemical Society. All rights reserved.

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页码：4210 / 4212

页数：3

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