STUDIES OF BORANES .24. SOME CHEMISTRY OF OCTABORANE-12 AND PREPARATION OF OCTABORANE-14

被引：37

作者：

DOBSON, J

SCHAEFFE.R

机构：

[1] Department of Chemistry, Indiana University, Bloomington

来源：

INORGANIC CHEMISTRY | 1968年 / 7卷 / 03期

关键词：

D O I：

10.1021/ic50061a002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Octaborane-12 has been found to be a strong monobasic Lewis acid; several compounds of the type B8H12·L were prepared. Octaborane-12 was nearly quantitatively converted to hexaborane-10 by limited hydrolysis and in about 45% yield to n-nonaborane-15 by diborane. A new octaborane, octaborane-14, was prepared from octaborane-12 in a two-step conversion. © 1968, American Chemical Society. All rights reserved.

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页码：402 / &

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