RECOVERY OF URANIUM FROM SEAWATER .5. PREPARATION AND PROPERTIES OF THE MACRORETICULAR CHELATING RESINS CONTAINING AMIDOXIME AND OTHER FUNCTIONAL-GROUPS

被引：60

作者：

EGAWA, H

NAKAYAMA, M

NONAKA, T

YAMAMOTO, H

UEMURA, K

机构：

[1] Kumamoto Univ, Kumamoto, Jpn, Kumamoto Univ, Kumamoto, Jpn

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 1987年 / 34卷 / 04期

关键词：

ADSORPTION - POLYMERS - Swelling - SEAWATER - Applications - URANIUM AND ALLOYS - Recovery;

D O I：

10.1002/app.1987.070340417

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The authors have synthesized macroreticular chelating resins containing amidoxime groups from acrylonitrile (AN)-divinylbenzene (DFB)-alkyl acrylate, alkyl methacrylate, or vinylpyridine (VPy) copolymer beads. It was found that the chelating resin (RNMH)-containing amidoxime groups prepared from AN-DVB-methyl acrylate (MA) indicated the highest adsorption ability for uranium in seawater. The adsorption ability for uranium was greatly influenced by the physical pore structure (macropore) and the pore structure formed by the swelling (micropore).

引用

页码：1557 / 1575

页数：19

共 17 条

[1] DEVELOPMENT OF SORBERS FOR THE RECOVERY OF URANIUM FROM SEAWATER .2. THE ACCUMULATION OF URANIUM FROM SEAWATER BY RESINS CONTAINING AMIDOXIME AND IMIDOXIME FUNCTIONAL-GROUPS [J].