COMPLETE RETENTION OF CONFIGURATION IN THE NUCLEOPHILIC-SUBSTITUTION OF 1-PHENYLBENZO[B]THIOPHENIUM SALTS BY ALKOXIDE ANIONS

被引：11

作者：

KITAMURA, T

MIYAJI, M

SODA, S

TANIGUCHI, H

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 13期

关键词：

D O I：

10.1039/c39950001375

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of 1,2,3-triarylbenzo[b]thiophenium salts with alkoxide anions results in:the exclusive formation of (Z) alkoxy-substituted alkenes, indicating that the nucleophilic ring-opening reaction proceeds with complete retention of configuration.

引用

页码：1375 / 1376

页数：2

共 38 条

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