COMPLETE RETENTION OF CONFIGURATION IN THE NUCLEOPHILIC-SUBSTITUTION OF 1-PHENYLBENZO[B]THIOPHENIUM SALTS BY ALKOXIDE ANIONS

被引:11
|
作者
KITAMURA, T
MIYAJI, M
SODA, S
TANIGUCHI, H
机构
关键词
D O I
10.1039/c39950001375
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Reaction of 1,2,3-triarylbenzo[b]thiophenium salts with alkoxide anions results in:the exclusive formation of (Z) alkoxy-substituted alkenes, indicating that the nucleophilic ring-opening reaction proceeds with complete retention of configuration.
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页码:1375 / 1376
页数:2
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