CORRELATION-EFFECTS IN SOLID C-60

被引:8
作者
LOF, RW
VANVEENENDAAL, MA
KOOPMANS, B
HEESSELS, A
JONKMAN, HT
SAWATZKY, GA
机构
来源
INTERNATIONAL JOURNAL OF MODERN PHYSICS B | 1992年 / 6卷 / 23-24期
关键词
D O I
10.1142/S0217979292002000
中图分类号
O59 [应用物理学];
学科分类号
摘要
The bandgap of solid C60 is found to be 2.3 +/- 0.1 eV. The on-site molecular C60 Coulomb interaction (U) as determined from the KVV C60 Auger spectrum is found to be 1.6 +/- .2 eV. This value of U is shown to be consistent with Frenkel type molecular excitons in the 1.5 - 2 eV range. These results lead us to suggest that doped C60 should be considered as a highly correlated system with U/W comparable to that in high T(c) cuprates. The Auger spectroscpoy results are consistent with a rather long range Coulomb interaction on a single bucky ball indicating that a Hubbard model is not suitable to describe the electronic structure of a C60 molecule.
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页码:3915 / 3921
页数:7
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