REFINING OF LIGNOCELLULOSE BY ORGANOSOLV PROCESSES .1. ISOLATION, CHARACTERIZATION AND UTILIZATION OF HEMICELLULOSE EXTRACTED FROM NORWAY SPRUCE

被引:10
作者
BENNANI, A [1 ]
RIGAL, L [1 ]
GASET, A [1 ]
机构
[1] ECOLE NATL SUPER CHIM TOULOUSE,INST NATL POLYTECH TOULOUSE,CHIM AGRORESSOURCES LAB,F-31077 TOULOUSE,FRANCE
关键词
ORGANOSOLV; HEMICELLULOSE; LIGNIN; GALACTOGLUCOMANNAN; ION EXCHANGER; LIGNIN HEMICELLULOSE COMPLEXES;
D O I
10.1016/0961-9534(91)90041-A
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
Analysis of the extract obtained from treatment of Norway Spruce (Picea abies) with a water-methanol mixture at high temperature (190-degrees-C) indicated hemicelluloses associated with lignin which formed a colloidal suspension when methanol was eliminated. Different analyses (IR, UV, GPC, HPLC, elementary microanalyses, etc...) showed that the hemicelluloses were galactoglucomannan (0.5-1-3) with a DP of 43, and that the lignin was of the guaicyl type. A separation process using strong acid and weak basic ion exchangers led to a lignin yield of 20% and to highly purified hemicelluloses representing 28% of the dry material.
引用
收藏
页码:289 / 296
页数:8
相关论文
共 20 条
[1]  
Myely, Nicholson, Katzen, Taylor, The forest refinery, Chemtech, 11, pp. 186-192, (1981)
[2]  
Edel, Das MD-organosolv-Zellstoffverfahren, Deutschepapierwirtschaft, 1, pp. 39-45, (1984)
[3]  
Norme Française homologuée, Determination de la teneur en pentosanes (par la méthode au furfural), (1975)
[4]  
Shield, Burnett, Determination of Protein-Bound Carbohydrate in Serum by Modified Anthrone Method, Analytical Chemistry, 32, pp. 885-886, (1960)
[5]  
Hamilton, Thompson, Pulp Pap. Mag. Can., 59, (1958)
[6]  
Abdennadher, Thèse de Docteur-Ingénieur, (1987)
[7]  
Hamilton, Thompson, A chemical comparaison of kraft and sulfite pulps, Pulp Pap. Mag Can, pp. 263-266, (1960)
[8]  
Timell, Isolation of galactoglucomannans from the wood of gymnosperms, Tappi, 44, 2, pp. 88-96, (1961)
[9]  
Erikson, Lindgren, About the linkage between lignin and hemicelluloses in wood, Sven. Papperstidn., 80, pp. 59-63, (1977)
[10]  
Linnell, Swenson, Structure of the black spruce glucomannan, Part III: Degree of branching and nature of the branch points, Tappi, 49, 11, pp. 494-497, (1966)