RHODIUM(I)-CATALYZED CYCLIZATIONS OF 3-C-ALKENYL PENTODIALDOSE DERIVATIVES

被引：56

作者：

GABLE, KP

BENZ, GA

机构：

[1] Department of Chemistry, Oregon State University, Corvallis

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 29期

基金：

美国国家卫生研究院;

关键词：

HYDROACYLATION; CARBOHYDRATES; CYCLIZATION; C-BRANCHED PENTODIALDOSE; ENE REACTION;

D O I：

10.1016/0040-4039(91)80809-K

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Cyclization of 1,2-isopropylidene 3-C-allyl ribo-pentodialdose, and 1-methylallyl and 3-C-vinyl analogs, with [(Ph3P)2RhCl]2 under CH2CH2 leads to intramolecular hydroacylation of the alkene with selective formation of cyclohexanones or cyclopentanones.

引用

收藏

页码：3473 / 3476

页数：4

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