OXYDEHYDROGENATION OF ALKYLBENZENES ON RH/ALPO4 CATALYSTS

被引：3

作者：

BAUTISTA, FM

CAMPELO, JM

GARCIA, A

LUNA, D

MARINAS, JM

机构：

[1] Organic Chemistry Department, Cordoba University, Cordoba, E-14004, San Alberto Magno Ave.

来源：

REACTION KINETICS AND CATALYSIS LETTERS | 1990年 / 41卷 / 02期

关键词：

D O I：

10.1007/BF02097884

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The oxidative dehydrogenation of several alkylbenzens has been carried out at 673-823 K on rhodium supported on AlPO4. A "compensation effect" between ΔH≠ and ΔS≠ activation parameters was obtained. This fact allows us to assume an identical mechanism for the dehydrogenation process when carried out on Rh/AlPO4 or on AlPO4 supports. Furthermore, the higher catalytic activity of the supports with respect to rhodium catalysts is explained by the higher number of acid sites in these supports. © 1990 Akadémiai Kiadó.

引用

页码：295 / 301

页数：7

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