PSEUDO-2-DIMENSIONAL IONIC CONDUCTORS - LI8MO6 (M=ZR, SN), LI7LO6 (L = NB, TA) AND LI6IN2O6

被引：35
作者：
DELMAS, C
MAAZAZ, A
GUILLEN, F
FOUASSIER, C
REAU, JM
HAGENMULLER, P
机构：
[1] Laboratoire de Chimie du Solide, C.N.R.S. Université de Bordeaux I 351 cours de la Libération
来源：
MATERIALS RESEARCH BULLETIN | 1979年 / 14卷 / 05期
关键词：
D O I：
10.1016/0025-5408(79)90044-8
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The ionic conductivity of the pseudo-2D oxides Li8MO6 (M = Zr, Sn), Li7LO6 (L = Nb, Ta) and Li6In2O6 has been measured and related to their structures. The ideal lattice consists of octahedral sheets [(Li2M)O6]n, [(Li□L)O6]n or [(In2□)O6]n of CdI2-type, between which 6 Li+ ions are inserted with a tetrahedral environment. As expected from the structures the highest lithium mobility is observed for Li7LO6 phases and the smallest one for Li8MO6. © 1979.
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页码：619 / 625
页数：7
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