MAGNETIC-STRUCTURE OF KFES2 - LINEAR-CHAIN ANTI-FERROMAGNET AND A SPIN ANALOG OF ACTIVE-SITES OF 2 IRON FERREDOXINS - BY NEUTRON-DIFFRACTION

被引:41
|
作者
NISHI, M
ITO, Y
机构
[1] Institute for Solid State Physics, The University of Tokyo, Tokyo, 106, Roppongi
关键词
D O I
10.1016/0038-1098(79)91138-4
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
Magnetic structure of KFeS2 - a spin analog of the oxidized two iron ferredoxins - was determined by the neutron diffraction method. Spins are antiferromagnetically coupled along the c-axis chain, and they make ferromagnetic sheets in the planes containing a and b axes below the transition temperature of 250.0 ± 0.5 K. The iron moment of 2.43 ± 0.03 μB lies in the a-c plane and is canted by 125.3 ± 0.7 degrees from a-axis at 4.2 K. © 1979.
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页码:571 / 574
页数:4
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