ELECTRON HOPPING IN MAGNETITE

被引:192
作者
KUNDIG, W
HARGROVE, RS
机构
[1] Department of Physics, University of California, Los Angeles
关键词
D O I
10.1016/0038-1098(69)90729-7
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
The Mössbauer spectrum of magnetite consists of two superimposed six line hyperfine spectra corresponding to A and B sites. The lines of the B site spectrum are broadened relative to those of the A site spectrum. It is suggested that the broadening is due to an electron exchange between the Fe3+ and Fe2+ ions at the B site. From the measured broadening it is possible to determine the relaxation time of the electron hopping. At room temperature the relaxation time is τ = (1.1±0.2) nsec. The results are compared with electrical conductivity data. © 1969.
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页码:223 / +
页数:1
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