SYNTHESIS, CHARACTERIZATION, AND CARBONYLATION OF THE ASYMMETRIC MONO-RING-FUNCTIONALIZED ZIRCONOCENES, (ETA(5)-C5H5)(ETA(5)-C5H4)P(C6H5)(2))ZR(CH3)X (X=CH3, CL)

被引：10

作者：

TIKKANEN, W

KIM, AL

LAM, KB

RUEKERT, K

机构：

[1] Department of Chemistry and Biochemistry, California State University Los Angeles, Los Angeles, California 90032

来源：

ORGANOMETALLICS | 1995年 / 14卷 / 03期

关键词：

D O I：

10.1021/om00003a066

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The preparation of alkyl, ring-functionalized zirconocenes, (eta(5)-C5H5)(eta(5)-C5H4)P(C6H5)(2))Zr(CH3)X(X = CH3 (1), X = CI (2)) is described. These compounds insert one molecule of CO to give products which interconvert between an acyl complex and a phosphonium alkoxide at ambient temperatures. The position of equilibrium between the acyl and phosphonium alkoxide complexes depends on the identity of X.

引用

页码：1525 / 1528

页数：4

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