Crystal structure of poly[aqua[mu-1,1'-(9,9-dimethyl-9H-fluoren-2,7-diyl) di-1H-imidazole](mu-naphthalene-1,4-dicarboxylato)nickel(II)]

被引:0
作者
Zou, Hengye [1 ]
Qi, Yanjuan [1 ]
机构
[1] Changchun Normal Univ, Dept Chem, Changchun 130032, Jilin, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2014年 / 70卷
关键词
crystal structure; nickel complex; naphthalene-1,4-dicarboxylate; hydrogen bonding; double chain;
D O I
10.1107/S1600536814017681
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, [Ni(C12H6O4)(C21H18N4)(H2O)](n), the Ni-II cation is coordinated by three carboxylate O atoms of two naphthalene-1,4-dicarboxylate anions, one water molecule and two N atoms of two 1,10-(9,9-dimethyl-9H-fluoren-2,7diyl) di-1H-imidazole (DFDI) ligands, giving rise to a slightly distorted octahedral geometry. The Ni-II ions are linked by the DFDI ligands into chains, which are further connected by the carboxylate anions into double chains that elongate in the the b-axis direction. These double chains are linked by centro-symmetric pairs of O-H center dot center dot center dot O hydrogen bonds into layers parallel to (10 (1) over bar). The asymmetric unit consists of one crystallographically independent Ni-II cation, one carboxylate and one DFDI ligand, as well as of one water molecule, all of them located in general positions.
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页码:M324 / +
页数:11
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