CATALYTIC ACTIVITY OF HOMOGENEOUS AND SILICA-ANCHORED RHODIUM COMPLEXES

被引:9
|
作者
CAPKA, M
CZAKOOVA, M
HJORTKJAER, J
SCHUBERT, U
机构
[1] UNIV WURZBURG, INST ANORGAN CHEM, W-8700 WURZBURG, GERMANY
[2] TECH UNIV DENMARK, DEPT CHEM ENGN, DK-2800 LYNGBY, DENMARK
来源
关键词
D O I
10.1007/BF02062191
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Using recently synthesized [1] (C2H5O)3Si(CH2)3 CH(COCH3)2 (1 underbar) and (CH3O)3Si(CH2)2-Py (2 underbar) (Py = 2-pyridyl), a series of homogeneous and silica-anchored rhodium carbonyl complexes were prepared. Their catalytic performance was studied in hydrogenation, hydrosilylation and methanol carbonylation.
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页码:71 / 74
页数:4
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