CATALYTIC ACTIVITY OF HOMOGENEOUS AND SILICA-ANCHORED RHODIUM COMPLEXES

被引:9
|
作者
CAPKA, M
CZAKOOVA, M
HJORTKJAER, J
SCHUBERT, U
机构
[1] UNIV WURZBURG, INST ANORGAN CHEM, W-8700 WURZBURG, GERMANY
[2] TECH UNIV DENMARK, DEPT CHEM ENGN, DK-2800 LYNGBY, DENMARK
来源
关键词
D O I
10.1007/BF02062191
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Using recently synthesized [1] (C2H5O)3Si(CH2)3 CH(COCH3)2 (1 underbar) and (CH3O)3Si(CH2)2-Py (2 underbar) (Py = 2-pyridyl), a series of homogeneous and silica-anchored rhodium carbonyl complexes were prepared. Their catalytic performance was studied in hydrogenation, hydrosilylation and methanol carbonylation.
引用
收藏
页码:71 / 74
页数:4
相关论文
共 50 条
  • [21] THE CHEMISTRY AND CATALYTIC ACTIVITY OF BINUCLEAR COMPLEXES OF RHODIUM(I)
    MAGUE, JT
    DEVRIES, SH
    DESSENS, SE
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1980, 180 (AUG): : 184 - INOR
  • [22] ON THE EFFECT OF DIBENZOPHOSPHOLE ON THE CATALYTIC ACTIVITY OF RHODIUM PHOSPHINE COMPLEXES
    HJORTKJAER, J
    DUEHOLM, H
    DEMELLO, PC
    JOURNAL OF MOLECULAR CATALYSIS, 1987, 39 (01): : 79 - 83
  • [23] Synthesis of Dibromobenzobarrelene Derivatives and Catalytic Activity of Their Rhodium Complexes
    Schlesinger, Maik
    Hofmann, Max
    Rueffer, Tobias
    Schaarschmidt, Dieter
    Lang, Heinrich
    Theilacker, Sergio
    Schuermann, Markus
    Jurkschat, Klaus
    Mehring, Michael
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2013, (16) : 2930 - 2939
  • [24] Silica-anchored organotin trichloride: a recyclable and clean organotin catalyst for transesterification reactions
    Toupance, Thierry
    Renard, Laetitia
    Jousseaume, Bernard
    Olivier, Celine
    Pinoie, Vanja
    Verbruggen, Ingrid
    Willem, Rudolph
    DALTON TRANSACTIONS, 2013, 42 (26) : 9764 - 9770
  • [25] RHODIUM PHOSPHINE COMPLEXES AS HOMOGENEOUS CATALYSTS .7. EFFECT OF PHOSPHINE STRUCTURE ON CATALYTIC ACTIVITY IN ACETONE HYDROGENATION
    VASTAG, S
    HEIL, B
    MARKO, L
    JOURNAL OF MOLECULAR CATALYSIS, 1979, 5 (03): : 189 - 195
  • [26] Silica-anchored CMPO-modified calix[4]arenes for radionuclide separations
    May, Erin M.
    Wanglee, Ying Jen
    Solovyov, Andrew
    Matveev, Yury
    Kalchenko, Vitaly
    Katz, Alexander
    Nitsche, Heino
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 248
  • [27] Mesoporous silica-anchored organotin as heterogeneous catalyst for the transesterification of dimethyl carbonate with phenol
    Zhang, Yuanzhuo
    Wang, Songlin
    Xiao, Zhongliang
    Chen, Tong
    Wang, Gongying
    RESEARCH ON CHEMICAL INTERMEDIATES, 2016, 42 (09) : 7213 - 7222
  • [28] Sonochemically-Promoted Preparation of Silica-Anchored Cyclodextrin Derivatives for Efficient Copper Catalysis
    Martina, Katia
    Calsolaro, Federica
    Zuliani, Alessio
    Berlier, Gloria
    Chavez-Rivas, Fernando
    Moran, Maria Jesus
    Luque, Rafael
    Cravotto, Giancarlo
    MOLECULES, 2019, 24 (13):
  • [29] Homogeneous Catalytic System for Photoinduced Hydrogen Production Utilizing Iridium and Rhodium Complexes
    Cline, Eric D.
    Adamson, Samantha E.
    Bernhard, Stefan
    INORGANIC CHEMISTRY, 2008, 47 (22) : 10378 - 10388
  • [30] A comparison between the homogeneous and the anchored rhodium skewphos catalyst
    Mahata, N
    Tanielyan, S
    Augustine, R
    Catalysis of Organic Reactions, 2005, 104 : 513 - 517