CATALYTIC ACTIVITY OF HOMOGENEOUS AND SILICA-ANCHORED RHODIUM COMPLEXES

被引：9

作者：

CAPKA, M

CZAKOOVA, M

HJORTKJAER, J

SCHUBERT, U

机构：

[1] UNIV WURZBURG, INST ANORGAN CHEM, W-8700 WURZBURG, GERMANY

[2] TECH UNIV DENMARK, DEPT CHEM ENGN, DK-2800 LYNGBY, DENMARK

来源：

REACTION KINETICS AND CATALYSIS LETTERS | 1993年 / 50卷 / 1-2期

关键词：

D O I：

10.1007/BF02062191

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Using recently synthesized [1] (C2H5O)3Si(CH2)3 CH(COCH3)2 (1 underbar) and (CH3O)3Si(CH2)2-Py (2 underbar) (Py = 2-pyridyl), a series of homogeneous and silica-anchored rhodium carbonyl complexes were prepared. Their catalytic performance was studied in hydrogenation, hydrosilylation and methanol carbonylation.

引用

页码：71 / 74

页数：4

共 10 条

[1] HYDROGENATION AND HYDROSILYLATION ACTIVITY OF HOMOGENEOUS AND IMMOBILIZED DICARBONYL(2,4-PENTANEDIONATO)RHODIUM COMPLEXES
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[9] METAL-COMPLEXES IN INORGANIC MATRICES .3. CATALYTIC ACTIVITY OF RH(CO)CL(PR3)2 HETEROGENISED BY THE SOL-GEL METHOD
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[10] AN EFFICIENT SYNTHESIS OF R3SI(CH2)N-SUBSTITUTED ACETYLACETONE DERIVATIVES
URBANIAK, W
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[J]. LIEBIGS ANNALEN DER CHEMIE, 1991, (11): : 1221 - 1223

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