PREPARATION OF OPTICALLY-ACTIVE (R)-ALLENE-1,3-DICARBOXYLATES AND (S)-ALLENE-1,3-DICARBOXYLATES AND THEIR ASYMMETRIC CYCLOADDITION REACTIONS WITH CYCLOPENTADIENE

被引：24

作者：

ASO, M

IKEDA, I

KAWABE, T

SHIRO, M

KANEMATSU, K

机构：

[1] KYUSHU UNIV 62,FAC PHARMACEUT SCI,INST SYNTHET ORGAN CHEM,HIGASHI KU,MAIDASHI,FUKUOKA 812,JAPAN

[2] RIGAKU CORP,AKISHIMA,TOKYO 196,JAPAN

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 39期

关键词：

OPTICALLY ACTIVE ALLENE-1,3-DICARBOXYLATE; ASYMMETRIC DIELS-ALDER REACTION;

D O I：

10.1016/0040-4039(92)89032-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Optically active (R)- and (S)-allene- 1,3-dicarboxylates were prepared, and their asymmetric Diels-Alder reactions with cyclopentadiene in the presence of Lewis acid proceeded to afford the endo-adducts in high yields. The absolute configuration of the adduct was completely confirmed by X-ray analysis.

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页码：5787 / 5790

页数：4

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