ELECTRONIC STRUCTURE AND CHEMICAL BOND OF COMPLEX La(NO3)(3)center dot bipy center dot 2H(2)O center dot(B-15-C-5)

被引：0

作者：

Dong Nan ^{[1
]}

Zhu Longguan ^{[1
]}

Wu Nianci ^{[1
]}

机构：

[1] Hangzhou Univ, Dept Chem, Hangzhou 310028, Zhejiang, Peoples R China

来源：

ACTA PHYSICO-CHIMICA SINICA | 1993年 / 9卷 / 02期

关键词：

INDO; Chemical bond; Electronic structure; La-complex compound;

D O I：

10.3866/PKU.WHXB19930221

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The electronic structure and chemical bonds in La(NO3)(3)center dot bipy center dot 2H(2)O center dot(B-15-C-5) has been studied by INDO method. The results indicated that 5d orbitals of La have largest contribution and 4f orbitals have hardly contribution in all valence orbitals of La in coordinate bonds of La-O and La-N. B-15-C-5 does not coordinate with La, but it effects formation of the complex and chemical bond.

引用

页码：252 / 255

页数：4

共 3 条

[1] CRYSTAL AND MOLECULAR STRUCTURE OF TRINITRATOBIS (BIPYRIDYL)LANTHANUM(III)
ALKARAGHOULI, AR
WOOD, JS
[J]. INORGANIC CHEMISTRY, 1972, 11 (10) : 2293 - +
[2] LANTHANIDE COMPLEXES .3. COMPLEXES OF 2,2'-DIPYRIDYL WITH LANTHANIDE CHLORIDES THIOCYANATES ACETATES AND NITRATES
HART, FA
LAMING, FP
[J]. JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1965, 27 (08): : 1825 - &
[3] CRYSTAL STRUCTURE OF DECACOORDINATED TERBIUM(3)-BIS-(2,2=-BIPYRIDYL)-TRIS-NITRATE - TB(NC5H4.C5H4N)2(NO3)3
MOSS, DS
SINHA, SP
[J]. ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-FRANKFURT, 1969, 63 (1-4): : 190 - &

← 1 →