RUTHENIUM(II) - CATALYZED OXIDATION OF ALCOHOLS BY PERSULFATE

被引：12

作者：

BRESSAN, M

FORTI, L

GHELFI, F

MORVILLO, A

机构：

[1] UNIV PADUA,DIPARTIMENTO CHIM ORGAN,VIA MARZOLO 1,I-35131 PADUA,ITALY

[2] UNIV MODENA,DIPARTIMENTO CHIM,I-41100 MODENA,ITALY

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1993年 / 79卷 / 1-3期

关键词：

ALCOHOLS; OXIDATION; PERSULFATE; RUTHENIUM;

D O I：

10.1016/0304-5102(93)85093-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Alcohols are oxidized to carbonylic compounds by aqueous persulfate in the presence of catalytic amounts (0.2%) of ruthenium trichloride and of a choice of ruthenium(II) complexes. Secondary alcohols are quantitatively converted to ketones, whereas primary alcohols can be converted to aldehydes with good selectivities. A kinetic investigation suggests a concerted mechanism for the bi-electronic oxygen transfer.

引用

页码：85 / 93

页数：9

共 47 条

[1] SELECTIVE OXIDATION OF ALCOHOLS BY A H2O2-RUCL3 SYSTEM UNDER PHASE-TRANSFER CONDITIONS
BARAK, G
DAKKA, J
SASSON, Y
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (15) : 3553 - 3555
[2] RUTHENIUM-CATALYZED OXIDATION OF PRIMARY ALCOHOLS WITH THE NEW OXIDATION SYSTEM N-METHYLMORPHOLINE/HYDROGEN-PEROXIDE
BEHR, A
EUSTERWIEMANN, K
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 403 (1-2) : 215 - 219
[3] THE SELECTIVE OXIDATION OF PRIMARY ALCOHOLS TO ALDEHYDES BY O-2 EMPLOYING A TRINUCLEAR RUTHENIUM CARBOXYLATE CATALYST
BILGRIEN, C
DAVIS, S
DRAGO, RS
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (12) : 3786 - 3787
[4] OXIDATIVE CLEAVAGE OF STYRENE WITH OXYGEN CATALYZED BY PHOSPHINORUTHENIUM(II) COMPLEXES
BONALDO, M
BORIN, F
BRESSAN, M
MORVILLO, A
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 363 (1-2) : 175 - 179
[5] ALKENE EPOXIDATION BY RUTHENIUM(II) PHOSPHINE COMPLEXES - A KINETIC INVESTIGATION
BRESSAN, M
MORVILLO, A
[J]. INORGANIC CHEMISTRY, 1989, 28 (05) : 950 - 953
[6] 5-COORDINATE AND 6-COORDINATE COMPLEXES OF OSMIUM(II) WITH 1,3-BIS(DIPHENYLPHOSPHINO)PROPANE
BRESSAN, M
ETTORRE, R
RIGO, P
[J]. INORGANICA CHIMICA ACTA, 1977, 24 (02) : L57 - L59
[7] 5-COORDINATE COMPLEXES OF RUTHENIUM(II) WITH DI(TERTIARY PHOSPHINES)
BRESSAN, M
RIGO, P
[J]. INORGANIC CHEMISTRY, 1975, 14 (09) : 2286 - 2288
[8] CATALYTIC EPOXIDATION OF ALKENES BY COORDINATIVELY UNSATURATED PHOSPHINO COMPLEXES OF RUTHENIUM(II) AND OSMIUM(II)
BRESSAN, M
MORVILLO, A
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (10) : 650 - 651
[9] SELECTIVE OXYGENATION OF ALIPHATIC ETHERS CATALYZED BY RUTHENIUM(II) COMPLEXES
BRESSAN, M
MORVILLO, A
ROMANELLO, G
[J]. INORGANIC CHEMISTRY, 1990, 29 (16) : 2976 - 2979
[10] SELECTIVE OXIDATION OF ALKANES AND ETHERS MEDIATED BY RUTHENIUM(II) COMPLEXES
BRESSAN, M
MORVILLO, A
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (07) : 421 - 423

← 1 2 3 4 5 →