ANTHRAQUINONE SULFONATE AS A GENERAL-PURPOSE SHIFT-REAGENT FOR THE NMR ANALYSIS OF CYCLODEXTRINS

被引：25

作者：

DJEDAINI, F

PERLY, B

机构：

[1] Commissariat À L'energie Atomique, Dlpc/Scm, Centre D'etudes Nucléaires de Saclay, Gif Sur Yvette

来源：

MAGNETIC RESONANCE IN CHEMISTRY | 1990年 / 28卷 / 04期

关键词：

!sup]1[!/sup]H NMR; Cyclodextrins; Molecular inclusion; Shift reagent;

D O I：

10.1002/mrc.1260280417

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The potential use of sodium anthraquinone 2‐sulphonate (ASANA) as a general‐purpose shift reagent for cyclodextrins is reported. It is demonstrated that completely resolved proton NMR spectra are obtained on inclusion of the host in the cavity of β‐and y‐cyclodextrins. The inclusion complexes have been characterized in terms of stoichiometry and association constants. Copyright © 1990 John Wiley & Sons, Ltd.

引用

页码：372 / 374

页数：3

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