PEROXIDES AS CONSTITUENTS OF PLANTS .15. IRREGULAR MONOTERPENE PEROXIDES FROM ACHILLEA-FILIPENDULINA LAM

被引：3
|
作者：
RUCKER, G [1 ]
MANNS, D [1 ]
KORBER, N [1 ]
BREUER, J [1 ]
机构：
[1] UNIV BONN, INST ANORGAN CHEM, D-53115 BONN, GERMANY
来源：
ARCHIV DER PHARMAZIE | 1994年 / 327卷 / 05期
关键词：
D O I：
10.1002/ardp.19943270502
中图分类号：
R914 [药物化学];
学科分类号：
100701 ;
摘要：
From Achillea filipendulina LAM. (Asteraceae) two hitherto unknown diastereomeric, irregular acyclic monoterpene peroxides 5, 6 of santolina triene type have been isolated (4alpha- and 4beta-peroxyachipendole). The constitution of 5 was confirmed by X-ray analysis. Reduction of 5 and 6 results in the formation of the alcohols 8 and 9, respectively. Constitutions of 8 and 9, reported in lit., have to be corrected. In addition, ascaridole (1), trans-pinocarveylhydroperoxide (2) and isolyratylhydroperoxide A (3) and B (4) have been found.
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页码：277 / 282
页数：6
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