EFFECT OF DEPOSITION PRESSURE ON THE MICROSTRUCTURE AND ELECTROCHROMIC PROPERTIES OF ELECTRON-BEAM-EVAPORATED NICKEL-OXIDE FILMS

被引：128
作者：
AGRAWAL, A
HABIBI, HR
AGRAWAL, RK
CRONIN, JP
ROBERTS, DM
CARONPOPOWICH, R
LAMPERT, CM
机构：
[1] LAWRENCE BERKELEY LAB,DIV ENERGY & ENVIRONM,BERKELEY,CA 94720
[2] DONNELLY CORP,HOLLAND,MI 49423
来源：
THIN SOLID FILMS | 1992年 / 221卷 / 1-2期
关键词：
D O I：
10.1016/0040-6090(92)90822-S
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Electron-beam-evaporated nickel oxide films were shown to have a microcrystalline cubic nickel oxide structure. The pressure in the chamber during the film deposition has a large effect on the crystal size and the stoichiometry of the films. The redox currents, the efficiency of these films to color, and their optical properties were influenced by the processing conditions employed and the resulting microstructure. A model is proposed based on the observed microstructure that explains the source of overstoichiometric oxygen and ion transport in these films.
引用
收藏
页码：239 / 253
页数：15
相关论文
共 29 条
[1]  
AGRAWAL PS, 1961, J PHYS CHEM-US, V65, P2105
[2]   NICKEL HYDROXIDE ELECTRODES .2. OXIDATION PRODUCTS OF NICKEL (2) HYDROXIDES [J].
BODE, H ;
DEHMELT, K ;
WITTE, J .
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1969, 366 (1-2) :1-&
[3]  
Briggs D, 1979, ELECTRON SPECTROSCOP, P305
[4]   APPLICATION OF ELECTRON-SPECTROSCOPY TO SURFACE STUDIES [J].
BRUNDLE, CR .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY, 1974, 11 (01) :212-224
[5]   THE ELECTROCHROMIC PROPERTIES OF HYDROUS NICKEL-OXIDE [J].
CARPENTER, MK ;
CONELL, RS ;
CORRIGAN, DA .
SOLAR ENERGY MATERIALS, 1987, 16 (04) :333-346
[6]   SYNTHESIS OF NEW DENSE PHASES OF OXYHYDROXIDES M(3+)OOH OF METALS OF FIRST TRANSITION SERIES IN HIGH-PRESSURE HYDROTHERMAL MEDIUM [J].
CHENAVAS, J ;
JOUBERT, JC ;
CAPPONI, JJ ;
MAREZIO, M .
JOURNAL OF SOLID STATE CHEMISTRY, 1973, 6 (01) :1-15
[7]   STRUCTURAL CONCEPTS IN INORGANIC PROTON CONDUCTORS [J].
CLEARFIELD, A .
SOLID STATE IONICS, 1991, 46 (1-2) :35-43
[8]   ELECTROCHROMIC BEHAVIOR OF NICKEL-OXIDE ELECTRODES .2. IDENTIFICATION OF THE BLEACHED STATE BY RAMAN-SPECTROSCOPY AND NUCLEAR-REACTIONS [J].
CORDOBATORRESI, SI ;
HUGOTLEGOFF, A ;
JOIRET, S .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1991, 138 (06) :1554-1559
[9]  
DELICHERE P, 1986, J ELECTROCHEM SOC, V135, P1856
[10]  
GLEMSER O, 1950, Z ANORGANISCHE ALLGM, V0261
123