PREPARATION AND PROPERTIES OF POLY(METHYLPYRIDINE-2,5-DIYL)S

被引：11
作者：
MARUYAMA, T
ZHOU, Z
KUBOTA, K
YAMAMOTO, T
机构：
[1] TOKYO INST TECHNOL, RESOURCES UTILIZAT RES LAB, 4259 NAGATSUTA, MIDORI KU, YOKOHAMA, KANAGAWA 227, JAPAN
[2] GUNMA UNIV, FAC ENGN, KIRYU, GUNMA 376, JAPAN
来源：
CHEMISTRY LETTERS | 1992年 / 04期
关键词：
D O I：
10.1246/cl.1992.643
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A series of poly(methylpyridine-2,5-diyl)s were synthesized by dehalogenation polycondensation of the corresponding 2,5-dibromo-methylpyridine with zerovalent nickel complexes. The polymers had molecular weight much higher than that of poly(pyridine-2,5-diyl). Poly(methylpyridine-2,5-diyl)s were converted into semiconducting material by chemical and electrochemical reduction (n-type doping).
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页码：643 / 646
页数：4
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