INSITU X-RAY-INVESTIGATION OF THE MELTING OF BI-SR-CA-CU-O PHASES

被引:78
作者
POLONKA, J [1 ]
XU, M [1 ]
LI, Q [1 ]
GOLDMAN, AI [1 ]
FINNEMORE, DK [1 ]
机构
[1] IOWA STATE UNIV SCI & TECHNOL,DEPT PHYS & ASTRON,AMES,IA 50011
关键词
D O I
10.1063/1.105605
中图分类号
O59 [应用物理学];
学科分类号
摘要
High-temperature x-ray studies of the melting of Bi2Sr2Ca1Cu2O8-delta/Ag composites have been undertaken in order to determine the factors that control the melting temperature and the various phases that form during the melt-processing part of the fabrication of these conductors. During the melting process, three distinct phases form and then dissolve in the Bi-rich liquid: first (Sr,Ca)1Cu1O2, then (Sr,Ca)2Cu1O3, and finally (Sr,Ca)O. Ag suppresses the melting point about 30-degrees-C and as much as 10% Ag can dissolve in the Bi-rich liquid. A slight Bi excess also decreases the temperature where the Bi2Sr2Ca1Cu2O8-delta structure disappears and liquid forms.
引用
收藏
页码:3640 / 3642
页数:3
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