LOCAL EXACT AND APPROXIMATE SOLUTIONS OF THE ADSORPTION INTEGRAL-EQUATION WITH A KERNEL OF A LANGMUIR-LIKE ISOTHERM - DETERMINATION OF ADSORPTION ENERGY-DISTRIBUTION

被引:38
作者
JAGIELLO, J
SCHWARZ, JA
机构
[1] SYRACUSE UNIV,DEPT CHEM ENGN & MAT SCI,SYRACUSE,NY 13244
[2] UNIV MIN MET,INST ENERGOCHEM COAL PHYSICOCHEM SORBENTS,PL-30059 KRAKOW,POLAND
关键词
D O I
10.1016/0021-9797(91)90206-N
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The local exact and approximate solutions of the adsorption integral equation are presented. The Langmuir-like adsorption isotherm is assumed as a kernel. The exact local solution is compared with Sips' method. The accuracy and resolution of truncated approximations are discussed. The influence of experimental temperature on calculated results is also considered. Lateral interactions are taken into account for the random topography model of the adsorption sites. © 1991.
引用
收藏
页码:415 / 424
页数:10
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