LARGE, MODE-SELECTIVE VIBRATIONAL EFFECT ON THE REACTION OF C2H2+ WITH METHANE

被引：51

作者：

CHIU, YH

FU, HS

HUANG, JT

ANDERSON, SL

机构：

[1] Department of Chemistry, State University of New York at Stony Brook, Stony Brook

来源：

JOURNAL OF CHEMICAL PHYSICS | 1994年 / 101卷 / 06期

关键词：

D O I：

10.1063/1.467394

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The reaction of C2H2+ with CH4 is strongly enhanced by excitation of a C2H2+ bending vibration, with little effect observed for the CC stretch. The enhancement results from efficient use of bending motion in surmounting an activation barrier Energy in the CC stretch has little effect on the threshold.

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页码：5410 / 5412

页数：3

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