ENZYMATIC POLYTRANSESTERIFICATION OF AROMATIC DIOLS IN ORGANIC-SOLVENTS

被引：11

作者：

PARK, HG

CHANG, HN

DORDICK, JS

机构：

[1] KOREA ADV INST SCI & TECHNOL,BIOPROC ENGN RES CTR,TAEJON 305701,SOUTH KOREA

[2] KOREA ADV INST SCI & TECHNOL,DEPT CHEM ENGN,TAEJON 305701,SOUTH KOREA

[3] UNIV IOWA,DEPT CHEM & BIOCHEM ENGN,IOWA CITY,IA 52242

来源：

BIOTECHNOLOGY LETTERS | 1995年 / 17卷 / 10期

关键词：

D O I：

10.1007/BF00143106

中图分类号：

Q81 [生物工程学（生物技术）]; Q93 [微生物学];

学科分类号：

071005 ; 0836 ; 090102 ; 100705 ;

摘要：

Enzymatic polytransesterification of aromatic diols was carried out in anhydrous organic solvents. The protease from Bacillus licheniformis catalyzed the polytransesterification of a diester of glutaric acid with aromatic diols such as benzenedimethanol. Gel permeation chromatography (GPC) provided Mw values of 400-1400 daltons for the aromatic polyesters. Bis(2,2,2-trifluoroethyl) glutarate and 1,4-benzenedimethanol. were used as model compounds to study the influence of aromaticity, solvent, and water content.

引用

页码：1085 / 1090

页数：6

共 8 条

[1]

APRK HG, 1994, BIOCATALYSIS, V11, P263

[2] DESIGNING ENZYMES FOR USE IN ORGANIC-SOLVENTS [J].