PALLADIUM-CATALYZED CHEMOSELECTIVE CLEAVAGE OF BETA-PROPARGYLOXY-ALPHA, BETA-UNSATURATED ESTERS - APPROACH TO GAMMA-PROTECTED HYDROXY-BETA-KETOESTERS

被引：9
|
作者：
SARIN, GS
机构：
[1] Division of Organic Synthesis, National Chemical Laboratory, Pune
来源：
TETRAHEDRON LETTERS | 1993年 / 34卷 / 39期
关键词：
CATALYSIS; CHEMOSELECTIVITY; HETEROLYTIC CLEAVAGE; BETA-KETOESTERS; PALLADIUM;
D O I：
10.1016/S0040-4039(00)73739-7
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Beta-Propargylaxy-alpha, beta-unsaturated esters 3a-e chemoselectively cleave in the presence of catalytic amount of Palladium (II) complexes to afford acid sensitive beta-ketoesters 4a-e in good yields.
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页码：6309 / 6312
页数：4
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