TRIPLET-STATE PHOTOEXCITATIONS IN FROZEN-SOLUTIONS OF OLIGOTHIOPHENES

被引:2
作者
JANSSEN, RAJ
MOSES, D
SARICIFTCI, NS
机构
[1] Institute for Polymers and Organic Solids, University of California, Santa Barbara
来源
MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 1994年 / 256卷
基金
美国国家科学基金会;
关键词
D O I
10.1080/10587259408039280
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
We present studies of near-steady-state photoinduced absorption (PIA) spectroscopy of well-defined alpha-oligothiophenes (T-n, n = 6,7,9, and 11) in frozen 2MeTHF solution. The PIA spectra and the excited state lifetimes are consistent with the signatures of a photoexcited triplet state. The triplet photoexcitation is created via an intrachain mechanism and decays nonradiatively with monomolecular kinetics.
引用
收藏
页码:487 / 492
页数:6
相关论文
共 14 条
[1]   PHOTOEXCITED STATES IN POLY(PARA-PHENYLENE VINYLENE) - COMPARISON WITH TRANS,TRANS-DISTYRYLBENZENE, A MODEL OLIGOMER [J].
COLANERI, NF ;
BRADLEY, DDC ;
FRIEND, RH ;
BURN, PL ;
HOLMES, AB ;
SPANGLER, CW .
PHYSICAL REVIEW B, 1990, 42 (18) :11670-11681
[2]   PHOTOCHEMICAL GENERATION OF RADICAL CATIONS FROM ALPHA-TERTHIENYL AND RELATED THIOPHENES - KINETIC-BEHAVIOR AND MAGNETIC-FIELD EFFECTS ON RADICAL-ION PAIRS IN MICELLAR SOLUTION [J].
EVANS, CH ;
SCAIANO, JC .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (07) :2694-2701
[3]   STOICHIOMETRIC CONTROL OF THE SUCCESSIVE GENERATION OF THE RADICAL CATION AND DICATION OF EXTENDED ALPHA-CONJUGATED OLIGOTHIOPHENES - A QUANTITATIVE MODEL FOR DOPED POLYTHIOPHENE [J].
FICHOU, D ;
HOROWITZ, G ;
XU, B ;
GARNIER, F .
SYNTHETIC METALS, 1990, 39 (02) :243-259
[4]   SPECTRA AND ELECTRICAL-PROPERTIES OF SOLUBLE PARTIALLY ALKYL-SUBSTITUTED OLIGOMERS OF THIOPHENE UP TO 11 RINGS [J].
HAVINGA, EE ;
ROTTE, I ;
MEIJER, EW ;
TENHOEVE, W ;
WYNBERG, H .
SYNTHETIC METALS, 1991, 41 (1-2) :473-478
[5]  
Huttenlocher D., 1993, ANGEW CHEM, V105, P125
[6]   OPTICAL SPECTROSCOPY OF HIGHLY ORDERED POLY(P-PHENYLENE VINYLENE) [J].
PICHLER, K ;
HALLIDAY, DA ;
BRADLEY, DDC ;
BURN, PL ;
FRIEND, RH ;
HOLMES, AB .
JOURNAL OF PHYSICS-CONDENSED MATTER, 1993, 5 (38) :7155-7172
[7]   CHROMISM OF SOLUBLE POLYTHIENYLENES [J].
RUGHOOPUTH, SDDV ;
HOTTA, S ;
HEEGER, AJ ;
WUDL, F .
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 1987, 25 (05) :1071-1078
[8]   PHOTOINDUCED ELECTRON-TRANSFER FROM A CONDUCTING POLYMER TO BUCKMINSTERFULLERENE [J].
SARICIFTCI, NS ;
SMILOWITZ, L ;
HEEGER, AJ ;
WUDL, F .
SCIENCE, 1992, 258 (5087) :1474-1476
[9]   SINGLET OXYGEN GENERATING EFFICIENCY OF ALPHA-TERTHIENYL AND SOME OF ITS SYNTHETIC ANALOGS [J].
SCAIANO, JC ;
MACEACHERN, A ;
ARNASON, JT ;
MORAND, P ;
WEIR, D .
PHOTOCHEMISTRY AND PHOTOBIOLOGY, 1987, 46 (02) :193-199
[10]   PHOTOEXCITATION SPECTROSCOPY OF CONDUCTING-POLYMER-C(60) COMPOSITES - PHOTOINDUCED ELECTRON-TRANSFER [J].
SMILOWITZ, L ;
SARICIFTCI, NS ;
WU, R ;
GETTINGER, C ;
HEEGER, AJ ;
WUDL, F .
PHYSICAL REVIEW B, 1993, 47 (20) :13835-13842