Isotopic Equilibria in the Hydrogen-Hydrogen Oxide System

被引：8

作者：

Crist, R. H. ^{[1
]}

Dalin, G. A. ^{[1
]}

机构：

[1] Columbia Univ, Dept Chem, New York, NY 10027 USA

来源：

JOURNAL OF CHEMICAL PHYSICS | 1934年 / 2卷 / 11期

关键词：

D O I：

10.1063/1.1749388

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Experiments are described in which the distribution of deuterium between hydrogen and water vapor at equilibrium at 800 degrees K is investigated. The equilibrium constants of the reactions necessary to describe the system H-2, HD, D-2, H2O, HDO and D2O are calculated and the amount of each constituent calculated for various concentrations of deuterium. The distribution of deuterium between the hydrogen and the water is calculated and found to agree with the experimental data.

引用

页数：4

共 18 条

[1] Rotation-vibration spectrum of water vapor [J].

Baumann, W. ;

Mecke, R. .

ZEITSCHRIFT FUR PHYSIK, 1933, 81 (7-8) :445-464

[2]

Bonhooffer KF, 1934, Z ELKTROCHEM ANGEW P, V40, P469

[3]

COFFIN CC, 1933, J AM CHEM SOC, V55, P3646

[4]

CRIST, 1934, J CHEM PHYS, V2, P548

[5]

CRIST, 1933, J CHEM PHYS, V1, P677

[6]

CRIST, 1934, J CHEM PHYS, V1, P442

[7]

CRIST, 1934, J CHEM PHYS, V2, P112

[8] The Equilibrium H2O+HD = HOD+H-2 and Its Role in the Separation of the Hydrogen Isotopes [J].

Farkas, A. ;

Farkas, L. .

JOURNAL OF CHEMICAL PHYSICS, 1934, 2 (08)

[9] Some experiments on heavy hydrogen [J].

Farkas, A ;

Farkas, L .

NATURE, 1933, 132 :894-894

[10]

FARKAS A, 1934, P ROY SOC A, V44, P467

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