Iron nanoparticles synthesized using green tea extracts for the fenton-like degradation of concentrated dye mixtures at elevated temperatures

Environmental harm caused by the release of textile dye contaminated wastewater from industry is an issue that requires immediate attention, particularly in developing countries. We herein demonstrate that green tea derived amorphous iron nanoparticles, in conjunction with Fenton like chemical processes, catabolise anthraquinone and azo dye mixtures that constitute a significant proportion of industrial dye waste. Iron nanoparticles, synthesized following a green tea mediated greener synthesis approach were able to degrade concentrated dye mixtures with over 90% decolourisation in only 20 min with 0.53 ppm nanoparticle concentration at a temperature of 70 degrees C. Detailed experimental degradation efficiencies were significantly pH and temperature dependant favouring lower pH values at temperatures between 70 and 90 degrees C, conditions which are commonly found in textile wastewaters. This research has shown the capacity for green tea synthesized nanoparticles to be used as a promoter for Fenton like dye degradation reactions. This rapid treatment approach may gain interest in the textile industries for dye waste remediation. (C) 2016 Published by Elsevier Ltd.