On the mechanism of the reaction K+HBr -> KBr+H

被引：16

作者：

Roach, A. C. ^{[1
]}

机构：

[1] Univ Manchester, Dept Chem, Manchester M13 9PL, Lancs, England

来源：

CHEMICAL PHYSICS LETTERS | 1970年 / 6卷 / 04期

关键词：

D O I：

10.1016/0009-2614(70)85102-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A potential-energy surface with a low barrier in the exit valley can account for large isotope effects observed in the reaction of K with HBr, DBr or TBr. Reaction is confined to a range of incident angles determined by the reactant translational and vibrational energies.

引用

页码：389 / 392

页数：4

共 15 条

[1] AIREY JR, 1964, J CHEM PHYS, V41, P1917
[2] THE DISSOCIATION ENERGIES OF GASEOUS ALKALI HALIDES
BREWER, L
BRACKETT, E
[J]. CHEMICAL REVIEWS, 1961, 61 (04) : 425 - 432
[3] ANALYTICAL SELF-CONSISTENT FIELD FUNCTIONS .3. ISOELECTRONIC SERIES WITH 19 TO 30 ELECTRONS
CLEMENTI, E
[J]. JOURNAL OF CHEMICAL PHYSICS, 1964, 41 (02) : 295 - &
[4] REACTIVE SCATTERING OF K BY HBR, DBR IN CROSSED MOLECULAR BEAMS - ANGULAR AND VELOCITY DISTRIBUTIONS OF KBR IN LABORATORY AND CM SYSTEMS
GILLEN, KT
RILEY, C
BERNSTEIN, RB
[J]. JOURNAL OF CHEMICAL PHYSICS, 1969, 50 (09) : 4019 - +
[5] THEORETICAL INVESTIGATION OF REACTIVE COLLISIONS IN MOLECULAR BEAMS - K+BR2
GODFREY, M
KARPLUS, M
[J]. JOURNAL OF CHEMICAL PHYSICS, 1968, 49 (08) : 3602 - &
[6] Herzberg G., 1950, SPECTRA DIATOMIC MOL, V1
[7] DISTRIBUTION OF REACTION PRODUCTS .V. REACTIONS FORMING AN IONIC BOND, M+XC (3D)
KUNTZ, PJ
MOK, MH
POLANYI, JC
[J]. JOURNAL OF CHEMICAL PHYSICS, 1969, 50 (11) : 4623 - &
[8] CROSSED MOLECULAR BEAM REACTIONS OF TRITIUM BROMIDE
MARTIN, LR
KINSEY, JL
[J]. JOURNAL OF CHEMICAL PHYSICS, 1967, 46 (12) : 4834 - &
[9] McClellan A. L., 1963, TABLES EXPT DIPOLE M
[10] MOLECULAR BEAM REACTION OF K WITH HC1 - EVIDENCE FOR AN ACTIVATION ENERGY
ODIORNE, TJ
BROOKS, PR
[J]. JOURNAL OF CHEMICAL PHYSICS, 1969, 51 (10) : 4676 - &

← 1 2 →