Synthesis, characterization and evaluation of fluorimetric chemosensors for ions based on diphenylimidazole derivatives

被引:0
作者
Ferreira, R. Cristina M. [1 ]
Costa, Susana P. G. [1 ]
Raposo, M. Manuela M. [1 ]
机构
[1] Univ Minho, Ctr Quim, Campus Gualtar, P-4710057 Braga, Portugal
来源
18TH INTERNATIONAL ELECTRONIC CONFERENCE ON SYNTHETIC ORGANIC CHEMISTRY | 2014年
关键词
Chemosensors; Imidazole; Radziszewski reaction; Thiophene; Fluorescence;
D O I
暂无
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The new 2,4,5-tri-substituted imidazole derivatives 2 and 3 were obtained in good yields through a Radziszewski reaction followed by alkylation. The new derivatives were characterized by the usual spectroscopic techniques and a detailed photophysical study was undertaken. The evaluation of the compounds as fluorimetric chemosensors was carried out by performing spectrofluorimetric titrations in acetonitrile in the presence of relevant organic and inorganic anions, and of alkaline, alkaline-earth and transition metal cations.
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页数:8
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共 7 条
[1]   Synthesis and characterization of novel (oligo)thienyl-imidazo-phenanthrolines as versatile π-conjugated systems for several optical applications [J].
Batista, Rosa M. F. ;
Costa, Susana P. G. ;
Belsley, M. ;
Lodeiro, Carlos ;
Raposo, M. Manuela M. .
TETRAHEDRON, 2008, 64 (39) :9230-9238
[2]   Naphthyl-imidazo-anthraquinones as novel colorimetric and fluorimetric chemosensors for ion sensing [J].
Batista, Rosa M. F. ;
Costa, Susana P. G. ;
Raposo, M. Manuela M. .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2013, 259 :33-40
[3]   Synthesis and biological activity of vicinal diaryl-substituted 1H-imidazoles [J].
Bellina, Fabio ;
Cauteruccio, Silvia ;
Rossi, Renzo .
TETRAHEDRON, 2007, 63 (22) :4571-4624
[4]   Fluorogenic and chromogenic chemosensors and reagents for anions [J].
Martínez-Máñez, R ;
Sancenón, F .
CHEMICAL REVIEWS, 2003, 103 (11) :4419-4476
[5]   FLUORESCENCE QUANTUM YIELD DETERMINATIONS - 9,10-DIPHENYLANTHRACENE AS A REFERENCE-STANDARD IN DIFFERENT SOLVENTS [J].
MORRIS, JV ;
MAHANEY, MA ;
HUBER, JR .
JOURNAL OF PHYSICAL CHEMISTRY, 1976, 80 (09) :969-974
[6]  
Pedras B., 2012, INORG CHIM ACTA, P381
[7]   Imidazoles as Potential Antifungal Agents: A Review [J].
Rani, Nidhi ;
Sharma, Ajay ;
Gupta, Girish Kumar ;
Singh, Randhir .
MINI-REVIEWS IN MEDICINAL CHEMISTRY, 2013, 13 (11) :1626-1655