(Z)-1-(2-Hydroxyethyl)-4-(2-methoxybenzylidene)-2-methyl-1H-imidazol-5(4H)-one

被引:0
|
作者
Wu, Hongyi [1 ]
Wang, Weihua [1 ]
Walker, Edwin H., Jr. [1 ]
Fronczek, Frank R. [2 ]
机构
[1] Southern Univ, Dept Chem, Baton Rouge, LA 70813 USA
[2] Louisiana State Univ, Dept Chem, Baton Rouge, LA 70803 USA
来源
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2013年 / 69卷
基金
美国国家科学基金会;
关键词
D O I
10.1107/S1600536813007770
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, C14H16N2O3, an analog of the chromophore in green fluorescent protein, the methoxyphenyl substituent and the imidazole N adopt a Z conformation with respect to the C = C bond. Aside from the hydroxyethyl group, the molecule is approximately planar, with the five- and six-membered ring planes forming a dihedral angle of 9.3 (1)degrees. An intramolecular C-H center dot center dot center dot N contact occurs. In the crystal, O-H center dot center dot center dot N hydrogen bonds link the molecules, forming chains along the b-axis direction. C-H center dot center dot center dot O hydrogen bonds are also observed.
引用
收藏
页码:O604 / +
页数:9
相关论文
共 50 条
  • [41] Unusual result of the reaction of 4-(1-methyl-1H-imidazol-2-yl)methylene-substituted 2-alkylthioimidazol-5(4H)-one with copper(II) chloride
    Yudina, A. V.
    Mazhuga, A. G.
    Beloglazkina, E. K.
    Yudin, I. V.
    Rodin, I. A.
    Zyk, N. V.
    RUSSIAN CHEMICAL BULLETIN, 2011, 60 (10) : 2120 - 2123
  • [42] (Z)-4-[(3-Aminonaphthalen-2-ylamino)(phenyl) methylidene]-3-methyl-1-phenyl1H-pyrazol- 5(4H)-one
    Zhang, Zhao
    Lu, Xingqiang
    Zhao, Shunsheng
    Liu, Xiangrong
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O2777 - +
  • [43] 4-[(2-Benzoyl-4-chlorophenyl)diazenyl]-3-methyl-1-phenyl-1H-pyrazol-5(4H)-one
    Bahreni, Zaker
    Rahmani, Hossein
    Ng, Seik Weng
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : O510 - U1705
  • [44] 1-(4-Chloro-2-fluoro-5-nitrophenyl)-4-difluoromethyl-3-methyl-1H-1,2,4-triazol-5(4H)-one
    Yang, Li
    Liu, Jun
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O1374 - +
  • [45] SYNTHESIS AND SCREENING OF (E)-1-(4-(2-(((PHENYLAMINO) METHYL) AMINO) ACETYL) PHENYL)-4-(2-PHENYLHYDRAZONO)-3(TRICHLOROMETHYL)-1H-PYRAZOL-5(4H)-ONE
    Ravinrdanath, L. K.
    Chakravarthi, B. V.
    Muralikrishna, S.
    HETEROCYCLIC LETTERS, 2014, 4 (04): : 587 - 596
  • [46] Synthesis, Crystal and Supermolecular Structure of (Z)-4-({4-[1-(Hydroxyimino)ethyl]-phenylimino}(phenyl) methyl)-3-methyl-1-phenyl-1H-pyrazol-5(4H)-one
    Dong, W. -K.
    Yang, Y. -H.
    Dong, X. -Y.
    Zhao, M. -M.
    Li, X.
    ASIAN JOURNAL OF CHEMISTRY, 2013, 25 (17) : 9952 - 9956
  • [47] 1-Anilino-2-hexylsulfanyl-4,4-dimethyl-1H-imidazol-5(4H)-one
    Sun, Shao-Fa
    Chen, Yu-Lu
    Li, Gui-Hua
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : O4219 - U2479
  • [48] 4-[(Z)-(n-Butylamino)(2-furyl)methyl- ene]-3-methyl-1-phenyl-1H-pyrazol-5 (4H)-one
    Zhang, Heng-Qiang
    Li, Jin-Zhou
    Zhang, Yong
    Zhang, Dan
    Su, Zhan-Hua
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : O3536 - U3747
  • [49] 1-(4-Chlorophenyl)-1H-1,2,4-triazol-5(4H)-one
    Kattimani, Pramod P.
    Kamble, Ravindra R.
    Kumbar, Mahadev N.
    Arunkashi, H. K.
    Devarajegowda, H. C.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : O499 - +
  • [50] 4-[3-(1H-Imidazol-1-yl)propyl]-3-phenyl-1H-1,2,4-triazol-5(4H)-one
    Kalkan, Hueseyin
    Ustabas, Resat
    Sancak, Kemal
    Uenver, Yasemin
    Vazquez-Lopez, Ezequiel M.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : O2449 - O2451