HETEROBIMETALLIC INDENYL COMPLEXES - SYNTHESIS AND STRUCTURE OF SYN-[CR(CO)(3)(MU,ETA,ETA-INDENYL)RH(COD)]

被引：34

作者：

BONIFACI, C

CECCON, A

GAMBARO, A

GANIS, P

SANTI, S

VALLE, G

VENZO, A

机构：

[1] UNIV PADUA,DIPARTIMENTO CHIM FIS,CHIM FIS RIC LAB,I-35131 PADUA,ITALY

[2] CNR,CTR STUDIO SUI BIOPOLIMERI,I-35131 PADUA,ITALY

[3] CNR,CTR STUDIO SUGLI STATI MOLEC RADICALI & ECCITATI,I-35131 PADUA,ITALY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 492卷 / 01期

关键词：

CHROMIUM; RHODIUM; INDENYL; SYN AND ANTI STRUCTURES; X-RAY STRUCTURE;

D O I：

10.1016/0022-328X(94)05280-O

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The heterobimetallic complex syn-[Cr(CO)(3)(mu,eta:eta-indenyl)Rh(COD)] was obtained by reaction of syn-[Cr(CO)(3)(mu,eta:eta-indenyl)Rh(CO)(2)] with COD. The stereochemistry was retained in the exchange reaction as confirmed by H-1 and C-13 NMR measurements and by X-ray diffractometric analysis. In spite of great distortion, the COD complex is quite stable. An unusual bonding interaction between the hybrid C=O orbitals of the Cr(CO)(3) group and the s-orbital of methine hydrogen atoms of COD is inferred on the basis of spectroscopic and X-ray structural data.

引用

页码：35 / 39

页数：5

共 50 条

[31] ELECTROCHEMICAL STUDIES OF AN OXIDATIVELY INDUCED RING SLIPPAGE IN 17-ELECTRON [ETA-3-INDENYL) (ETA-5-INDENYL)V(CO)2]
MILLER, GA
THERIEN, MJ
TROGLER, WC
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1987, 193 : 19 - INOR
[32] FORMATION AND STRUCTURE OF BIS(DIPHENYLPHOSPHINO)ETHANE BIS(INDENYL)MOLYBDENUM(II), A COMPOUND WITH ONE ETA-3 AND ONE ETA-5 INDENYL LIGAND
POLI, R
MATTAMANA, SP
FALVELLO, LR
GAZZETTA CHIMICA ITALIANA, 1992, 122 (08): : 315 - 319
[33] CHARACTERIZATION OF A STABLE (ETA-3-INDENYL)IRON METALATE, (ETA-3-C9H7)FE(CO)3- - A ROLE FOR ETA-3-ETA-5 INDENYL LIGAND TAUTOMERIZATION DURING ALKYL CO INSERTION REACTIONS
FORSCHNER, TC
CUTLER, AR
KULLNIG, RK
ORGANOMETALLICS, 1987, 6 (04) : 889 - 891
[34] SYNTHESIS, MOLECULAR-STRUCTURE, SOLUTION DYNAMICS, AND REACTIVITY OF (ETA-C5H5)2M(MU-PR2)2RH(ETA-INDENYL) (M = ZR, HF R = ET, PH)
BAKER, RT
TULIP, TH
ORGANOMETALLICS, 1986, 5 (05) : 839 - 845
[35] Indenyl Co(I) complexes: Synthesis, structure, and reactivity
Hung-Low, Fernando
Bradley, Christopher A.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2010, 240
[36] THE SLIP-FOLD DISTORTION OF PI-BOUND INDENYL LIGANDS - DYNAMIC NMR AND X-RAY CRYSTALLOGRAPHIC STUDIES OF (ETA-INDENYL)RHL2 COMPLEXES
MARDER, TB
CALABRESE, JC
ROE, DC
TULIP, TH
ORGANOMETALLICS, 1987, 6 (09) : 2012 - 2014
[37] STRUCTURE OF TETRAKIS(1-3-ETA-2-INDENYL)THORIUM(IV)
REBIZANT, J
SPIRLET, R
KANELLAKOPULOS, B
DORNBERGER, E
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1986, 42 : 1497 - 1500
[38] BASIC METALS .22. SYNTHESIS AND REACTIVITY OF ETA-5-INDENYL-TRIMETHYLPHOSPHANERHODIUM(I) AND INDENYL-RHODIUM(III) COMPLEXES
WERNER, H
FESER, R
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1980, 35 (06): : 689 - 693
[39] Heterobimetallic indenyl complexes. Mechanism of cyclotrimerization of dimethyl acetylenedicarboxylate (DMAD) catalyzed by trans-[Cr(CO)(3)(heptamethylindenyl)Rh(CO)(2)]
Mantovani, L
Ceccon, A
Gambaro, A
Santi, S
Ganis, P
Venzo, A
ORGANOMETALLICS, 1997, 16 (12) : 2682 - 2690
[40] Electrochemical synthesis of eta(5)-indenyl-eta(5)-(3)-1,2-dicarbollyliron(III)
Shirokii, VL
Knizhnikov, VA
Vinokurov, II
Bazhanov, AV
Ryabtsev, AN
Maier, NA
ZHURNAL OBSHCHEI KHIMII, 1997, 67 (03): : 401 - 403

← 1 2 3 4 5 →