HETEROBIMETALLIC INDENYL COMPLEXES - SYNTHESIS AND STRUCTURE OF SYN-[CR(CO)(3)(MU,ETA,ETA-INDENYL)RH(COD)]

被引：34
|
作者：
BONIFACI, C
CECCON, A
GAMBARO, A
GANIS, P
SANTI, S
VALLE, G
VENZO, A
机构：
[1] UNIV PADUA,DIPARTIMENTO CHIM FIS,CHIM FIS RIC LAB,I-35131 PADUA,ITALY
[2] CNR,CTR STUDIO SUI BIOPOLIMERI,I-35131 PADUA,ITALY
[3] CNR,CTR STUDIO SUGLI STATI MOLEC RADICALI & ECCITATI,I-35131 PADUA,ITALY
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 492卷 / 01期
关键词：
CHROMIUM; RHODIUM; INDENYL; SYN AND ANTI STRUCTURES; X-RAY STRUCTURE;
D O I：
10.1016/0022-328X(94)05280-O
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The heterobimetallic complex syn-[Cr(CO)(3)(mu,eta:eta-indenyl)Rh(COD)] was obtained by reaction of syn-[Cr(CO)(3)(mu,eta:eta-indenyl)Rh(CO)(2)] with COD. The stereochemistry was retained in the exchange reaction as confirmed by H-1 and C-13 NMR measurements and by X-ray diffractometric analysis. In spite of great distortion, the COD complex is quite stable. An unusual bonding interaction between the hybrid C=O orbitals of the Cr(CO)(3) group and the s-orbital of methine hydrogen atoms of COD is inferred on the basis of spectroscopic and X-ray structural data.
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收藏
页码：35 / 39
页数：5
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