ULTRAHARD AND SUPERHARD CARBON PHASES PRODUCED FROM C-60 BY HEATING AT HIGH-PRESSURE - STRUCTURAL AND RAMAN STUDIES

被引：154

作者：

BLANK, VD ^{[1
]}

BUGA, SG ^{[1
]}

SEREBRYANAYA, NR ^{[1
]}

DENISOV, VN ^{[1
]}

DUBITSKY, GA ^{[1
]}

IVLEV, AN ^{[1
]}

MAVRIN, BN ^{[1
]}

POPOV, MY ^{[1
]}

机构：

[1] SCI & TECH CTR SUPERHARD MAT,TROITSK 142092,RUSSIA

来源：

PHYSICS LETTERS A | 1995年 / 205卷 / 2-3期

关键词：

D O I：

10.1016/0375-9601(95)00564-J

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

Investigations of X-ray diffraction patterns, Raman spectra, hardness and other physical properties were carried out for fullerite after a heat treatment up to 1830 K at 9.5 and 13 GPa nonhydrostatic pressure of bulk samples. Both superhard and ultrahard forms of carbon have been obtained from C-60 at 620-1830 K. The hardness of the materials exceeded that of diamond. The X-ray and Raman measurements have shown that both crystal structures and fullerene molecules were retained in superhard and ultrahard states, but a gradual increase of disorder occurred and a random network of linked molecules at high temperatures was formed.

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页码：208 / 216

页数：9

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[41] Preparation and study of high-pressure phases of C60 fullerene [J].

Kozlov, M.E. ;

Tokumoto, M. ;

Yakushi, K. .

Synthetic Metals, 1997, 86 (1 -3 pt 3) :2349-2350

[42] Packing models for high-pressure polymeric phases of C60 [J].

Davydov, VA ;

Agafonov, V ;

Dzyabchenko, AV ;

Céolin, R ;

Szwarc, H .

JOURNAL OF SOLID STATE CHEMISTRY, 1998, 141 (01) :164-167

[43] RAMAN STUDIES ON C-60 AT HIGH-PRESSURES AND LOW-TEMPERATURES [J].

TOLBERT, SH ;

ALIVISATOS, AP ;

LORENZANA, HE ;

KRUGER, MB ;

JEANLOZ, R .

CHEMICAL PHYSICS LETTERS, 1992, 188 (3-4) :163-167

[44] Raman and X-ray scattering studies of high-pressure phases of urea [J].

Lamelas, FJ ;

Dreger, ZA ;

Gupta, YM .

JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (16) :8206-8215

[45] STUDIES ON THE HIGH-PRESSURE PHASES OF POLYETHYLENE AND POLY(TETRAFLUOROETHYLENE) BY RAMAN-SPECTROSCOPY [J].

TANAKA, H ;

TAKEMURA, T .

POLYMER JOURNAL, 1980, 12 (06) :355-361

[46] STRUCTURAL STUDIES OF HIGH-PRESSURE BA-RH-O PHASES [J].

SIEGRIST, T ;

LARSON, EM ;

CHAMBERLAND, BL .

JOURNAL OF ALLOYS AND COMPOUNDS, 1994, 210 (1-2) :13-17

[47] Structural studies of high-pressure Ba-Rh-O phases [J].

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[48] High-pressure synthesis of novel superhard phases in the B-C-N system: recent achievements [J].

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HIGH PRESSURE RESEARCH, 2009, 29 (04) :612-617

[49] Structures and physical properties of superhard and ultrahard 3D polymerized fullerites created from solid C60 by high pressure high temperature treatment [J].

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Buga, SG ;

Serebryanaya, NR ;

Dubitsky, GA ;

Mavrin, BN ;

Popov, MY ;

Bagramov, RH ;

Prokhorov, VM ;

Sulyanov, SN ;

Kulnitskiy, BA ;

Tatyanin, YV .

FULLERENES AND CARBON BASED MATERIALS, 1998, 68 :665-670

[50] Structures and physical properties of superhard and ultrahard 3D polymerized fullerites created from solid C60 by high pressure high temperature treatment [J].

Blank, VD ;

Buga, SG ;

Serebryanaya, NR ;

Dubitsky, GA ;

Mavrin, BN ;

Popov, MY ;

Bagramov, RH ;

Prokhorov, VM ;

Sulyanov, SN ;

Kulniskiy, BA ;

Tatyanin, YV .

CARBON, 1998, 36 (5-6) :665-670

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