A CONVENIENT APPROACH TO PERFLUORINATED ORGANOSILICONS, PREPARATION OF A FLUORINATED POLYSILOXANE PRECURSOR

被引：4

作者：

BEYOU, E

BABIN, P

BENNETAU, B

DUNOGUES, J

TEYSSIE, D

BOILEAU, S

机构：

[1] UNIV BORDEAUX 1,CNRS,CHIM ORGAN & ORGANOMET LAB,F-33405 TALENCE,FRANCE

[2] COLL FRANCE,F-75231 PARIS 05,FRANCE

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 11期

关键词：

D O I：

10.1016/0040-4039(95)00137-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Addition of perfluoroctyl iodide to the double bonds of vinyltrimethylsilane and 1,3-divinyltetramethyldisiloxane, followed by a reduction of the carbon-iodide bond. gives the corresponding C8F17CH2CH(2)Si= moiety. Following this approach. [C8F17-CH2CH2-Si(Me)O](4) a precursor of highly fluorinated silicones, was conveniently prepared, without using hydrosilylation or Grignard reaction.

引用

页码：1843 / 1844

页数：2

共 7 条

[1]

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[3]

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[4]

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[5]

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[6]

NEUMANN WP, 1987, SYNTHESIS-STUTTGART, P665

[7] THE ADDITION OF PERFLUOROBUTYL IODIDE TO CARBON-CARBON MULTIPLE BONDS AND THE PREPARATION OF PERFLUOROBUTYLALKENES [J].

RONG, GB ;

KEESE, R .

TETRAHEDRON LETTERS, 1990, 31 (39) :5615-5616

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