A DINUCLEAR ZINC HYDROXIDE COMPLEX WHICH TRAPS ATMOSPHERIC CARBON-DIOXIDE - FORMATION OF A TRI-ZINC COMPLEX WITH A TRIPLY BRIDGING CARBONATE GROUP

被引：111

作者：

MURTHY, NN ^{[1
]}

KARLIN, KD ^{[1
]}

机构：

[1] JOHNS HOPKINS UNIV,DEPT CHEM,BALTIMORE,MD 21218

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 15期

关键词：

D O I：

10.1039/c39930001236

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Dinuclear di-mu-hydroxo zinc(II)complex 1, containing a tetradentate nitrogen ligand, readily absorbs atmospheric CO2 to form tri-zinc complex 2, containing an uncommon triply bridging carbonate group; the structures of 1 and 2 have been established by X-ray crystallography.

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页码：1236 / 1238

页数：3

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