DIOXALANONES AS SYNTHETIC INTERMEDIATES .6. SYNTHESIS OF 3-DEOXY-D-MANNO-2-OCTULOSONIC ACID (KDO), 3-DEOXY-D-ARABINO-2-HEPTULOSONIC ACID (DAH) AND 2-KETO-3-DEOXY-D-GLUCONIC ACID (KDG)

被引：40

作者：

RAMAGE, R ^{[1
]}

MACLEOD, AM ^{[1
]}

ROSE, GW ^{[1
]}

机构：

[1] UNIV MANCHESTER,INST SCI & TECHNOL,DEPT CHEM,MANCHESTER M60 1QD,LANCS,ENGLAND

来源：

TETRAHEDRON | 1991年 / 47卷 / 29期

关键词：

D O I：

10.1016/S0040-4020(01)80993-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Three biosynthetically significant alpha-keto acids KDO (7), DAH (8) and KDG (9) have been synthesised via 5-ylidene-1,3-dioxalan-4-one intermediates formed by Wittig reactions of protected monosaccharide-derived aldehydes with the Wittig reagent (3).

引用

页码：5625 / 5636

页数：12

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