PERFLUOROACYL THIOPHENS .I. BEHAVIOUR OF 2-THIENYL METALS WITH PERFLUOROALIPHATIC ACID DERIVATIVES

被引：5

作者：

JONES, E

MOODIE, IM

机构：

[1] Arthur D. Little Research Institute, Musselburgh, Midlothian

[2] Department of Organic Chemistry, The University, Groningen

来源：

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1968年 / 10期

关键词：

D O I：

10.1039/j39680001195

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of 2-thienyl-lithium with perfluoroaliphatio acids and their NN-diethyl amides gives anomalous results; either a perfluoroacyl thiophen or a thiophen-carboxylic acid or carboxamide is obtained, depending on the size of the perfluoroalkyl group. Hexafluoro-1,3-di-(2-thenoyl)propane has been prepared from 2-thienyl-magnesium bromide and perfluoroglutaryl dichloride.

引用

页码：1195 / &

共 19 条

[1]

BELLAMY LJ, 1958, INFRARED SPECTRA COM, P330

[2]

BELLAMY LJ, 1958, INFRARED SPECTRA COM, P137

[3] INTERMEDIATES IN THE REACTIONS OF CARBOXYLIC ACID DERIVATIVES .2. INFRARED ABSORPTION SPECTRA AS EVIDENCE FOR THE FORMATION OF ADDITION COMPOUNDS OF CARBOXYLIC ACID DERIVATIVES [J].

BENDER, ML .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1953, 75 (23) :5986-5990

[4]

BRAENDLIN HP, 1963, ADV FLUORINE CHEM, V3, P2

[5]

CHEN CY, 1966, CA 5351D, V65

[6]

Chen Q., 1966, ACTA CHIM SINICA, V32, P18

[7]

CLARK HC, 1963, ADV FLUORINE CHEM, V3, P53

[8] METALATION OF THIOPHENE BY NORMAL-BUTYLLITHIUM [J].

GILMAN, H ;

SHIRLEY, DA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1949, 71 (05) :1870-1871

[9]

GRONOWITZ S, 1963, ADV HETEROCYCLIC CHE, V1, pCH1

[10]

HARTOUGH HD, 1952, THIOPHENE ITS DERIVA, P375

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