S-33 NUCLEAR-MAGNETIC-RESONANCE SPECTRA FOR SULFATES

被引：2
|
作者：
KOSUGI, Y [1 ]
OKAZAKI, H [1 ]
机构：
[1] NIPPON STEEL CHEM CO LTD,RES & DEV LABS,ORGAN CHEM GRP,TOBATA 804,JAPAN
来源：
ANALYTICAL SCIENCES | 1991年 / 7卷 / 06期
关键词：
S-33 NUCLEAR MAGNETIC RESONANCE SPECTRUM; SULFURIC ACID; SULFATE; ORGANIC SULFATE; THIOSULFATE; CONFIGURATIONAL SYMMETRY;
D O I：
10.2116/analsci.7.849
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
The sulfur-33 NMR spectra at natural abundance for sodium, cupric, cadmium and cesium sulfates besides sulfuric acid were recorded. Ferric and nickel sulfates did not give spectra because of their strong ferromagnetism. A very sharp peak at 33.5 ppm downfield from ammonium sulfate was observed for sodium thiosulfate. Dimethylsulfate and ethane sulfate also showed spectra with a poor signal-to-noise ratio, with accumulations of 10(5) transients at 19.19 MHz.
引用
收藏
页码：849 / 851
页数：3
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