DEHALOGENATION OF ISODRIN AND ALDRIN WITH ALKOXIDE BASES

被引：36
作者：
ADAMS, CHM
MACKENZI.K
机构：
来源：
JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1969年 / 03期
关键词：
D O I：
10.1039/j39690000480
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Earlier reports suggest that isodrin and aldrin and their derivatives are unreactive towards, e.g., sodium methoxide. The present work describes the largely stereospecific dechlorination of isodrin and aldrin and related fused polychloro-norbornenes with sodium methoxide in methanol-dimethyl sulphoxide. The stereochemistry of the products is established and a unique long-range 1H n.m.r. coupling over six bonds reported in a related system.
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页码：480 / &
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