ELECTROLYTIC SAMPLE PRETREATMENT IN ATOMIC SPECTROMETRY - A REVIEW

被引：22
作者：
BEINROHR, E
机构：
[1] Department of Analytical Chemistry, Slovak Technical University, Bratislava
来源：
MIKROCHIMICA ACTA | 1995年 / 120卷 / 1-4期
关键词：
REVIEW; ELECTRODEPOSITION; ELECTROLYSIS; PRECONCENTRATION; ATOMIC SPECTROMETRY;
D O I：
10.1007/BF01244418
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
The use of electrolysis in analytical atomic spectrometry is reviewed. Topics such as electrodeposition for analyte enrichment, electrochemical sample pretreatment and hydride generation are discussed. The use of batch and flow-through electrochemical cells is compiled and critically evaluated. Flow-through cells with porous working electrodes were found to provide the best performance for analyte enrichment.
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页码：39 / 52
页数：14
相关论文
共 58 条
[1]  
Bard A. J., 2001, ELECTROCHEMICAL METH, V2nd, P50
[2]   DETERMINATION OF CHROMIUM SPECIATION IN NATURAL-WATERS BY ELECTRODEPOSITION ON GRAPHITE TUBES FOR ELECTROTHERMAL ATOMIZATION [J].
BATLEY, GE ;
MATOUSEK, JP .
ANALYTICAL CHEMISTRY, 1980, 52 (11) :1570-1574
[3]   DETERMINATION OF HEAVY-METALS IN SEAWATER BY ATOMIC-ABSORPTION SPECTROMETRY AFTER ELECTRODEPOSITION ON PYROLYTIC GRAPHITE-COATED TUBES [J].
BATLEY, GE .
ANALYTICAL CHEMISTRY, 1977, 49 (13) :2031-2035
[4]   DETERMINATION OF PLATINUM IN BIOTIC AND ENVIRONMENTAL-SAMPLES BY GRAPHITE-FURNACE ATOMIC-ABSORPTION SPECTROMETRY AFTER ITS ELECTRODEPOSITION INTO A GRAPHITE TUBE PACKED WITH RETICULATED VITREOUS CARBON [J].
BEINROHR, E ;
LEE, ML ;
TSCHOPEL, P ;
TOLG, G .
FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY, 1993, 346 (6-9) :689-692
[5]   ONLINE ELECTROCHEMICAL PRECONCENTRATION OF MANGANESE FOR GRAPHITE-FURNACE ATOMIC-ABSORPTION SPECTROMETRY USING A FLOW-THROUGH ELECTROCHEMICAL-CELL [J].
BEINROHR, E ;
RAPTA, M ;
LEE, ML ;
TSCHOPEL, P ;
TOLG, G .
MIKROCHIMICA ACTA, 1993, 110 (1-3) :1-12
[6]   ELECTROLYTICAL MICROCELL FOR ONLINE PRECONCENTRATION OF TRACE-METALS IN FLOW SYSTEMS [J].
BEINROHR, E .
FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY, 1990, 338 (06) :735-737
[7]   DESIGN AND CHARACTERIZATION OF FLOW-THROUGH COULOMETRIC CELLS WITH POROUS WORKING ELECTRODES MADE OF CRUSHED VITREOUS CARBON [J].
BEINROHR, E ;
NEMETH, M ;
TSCHOPEL, P ;
TOLG, G .
FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY, 1992, 343 (07) :566-575
[8]   DESIGN AND EVALUATION OF AN ONLINE MICROCOLUMN PRE-CONCENTRATION TECHNIQUE FOR GRAPHITE-FURNACE ATOMIC-ABSORPTION SPECTROMETRY [J].
BEINROHR, E ;
CAKRT, M ;
RAPTA, M ;
TARAPCI, P .
FRESENIUS ZEITSCHRIFT FUR ANALYTISCHE CHEMIE, 1989, 335 (08) :1005-1007
[9]   DETERMINATION OF LEAD BY ELECTROTHERMAL VAPORIZATION MICROWAVE-INDUCED PLASMA-ATOMIC EMISSION-SPECTROMETRY AFTER FLOW-THROUGH ELECTROLYTIC DEPOSITION IN A GRAPHITE TUBE PACKED WITH RETICULATED VITREOUS CARBON [J].
BEINROHR, E ;
BULSKA, E ;
TSCHOPEL, P ;
TOLG, G .
JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 1993, 8 (07) :965-968
[10]   PRE-CONCENTRATION OF TRACE-METALS FROM ACIDIC SAMPLE SOLUTIONS ON A THIN-LAYER OF ACTIVATED CARBON USING DITHIZONE AS A CHELATING AGENT [J].
BEINROHR, E ;
ROJCEK, J ;
GARAJ, J .
ANALYST, 1988, 113 (12) :1831-1835
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