ELECTROCATALYTIC OXIDATION OF SACCHAROSE IN ALKALINE-MEDIUM

被引：43

作者：

PARPOT, P

KOKOH, KB

BEDEN, B

LAMY, C

机构：

[1] Laboratoire de Chimie I, URA-CNRS 350, Université de Poitiers, 86022 Poitiers Cedex, 40, avenue du Recteur Pineau

来源：

ELECTROCHIMICA ACTA | 1993年 / 38卷 / 12期

关键词：

CYCLIC VOLTAMMETRY; OXIDATION; IONIC CHROMATOGRAPHY; SACCHAROSE (SUCROSE); ELECTROLYSIS;

D O I：

10.1016/0013-4686(93)85058-7

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The electrocatalytic oxidation of saccharose solutions was carried out in alkaline medium on various noble and non-noble electrodes, with the aim of checking the electroreactivity of saccharose and its potentiality as a raw material for electrosynthesis. The best electrocatalytic activity was obtained with gold. In this latter case, chromatographic analysis of electrolysed solutions allowed us to identify numerous monocarboxylic acids, some of them resulting from the breaking of the C-O-C bond.

引用

页码：1679 / 1683

页数：5

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