STRUCTURE OF MU-(TEREPHTHALATO)-BIS[N,N'-ETHYLENEBIS(SALICYLALDIMINATO)IRON(III)]

被引:10
作者
DUSEK, M [1 ]
PETRICEK, V [1 ]
KAMENICEK, J [1 ]
SINDELAR, Z [1 ]
机构
[1] PALACKY UNIV, FAC SCI, INST INORGAN & PHYS CHEM, CS-77147 OLOMOUC, CZECHOSLOVAKIA
来源
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 1992年 / 48卷
关键词
D O I
10.1107/S0108270192000982
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Mu-(1,4-benzenedicarboxylato-O,O':O,"O"')-bis {2,2'-[1,2-ethanediylbis(iminomethyl)]diphenolato-N,N',O,O'}diiron(III), [Fe2(C16H14N2O2)2-(C8H4O4)], M(r) = 808.41, monoclinic, P2(1)/c, a = 6.954 (1), b = 17.196 (3), c = 15.333 (2) angstrom, beta = 99.53 (1)-degrees, V = 1808.2 (5) angstrom3, Z = 2, D(m) = 1.51, D(x) = 1.48 g cm-3, lambda(Cu Kalpha) = 1.5418 angstrom, mu = 68.48 cm-1, F(000) = 832, T = 293 K, R = 0.072 for 2432 observed reflections. The crystal used for the structure determination was a twin with partially coinciding reflections and the twin ratio alpha = 0.4936 (3). The molecule [Fe(salen)]2ter, where salen = N,N'-ethylenebis(salicylaldiminato) and ter = mu-(terephthalato), consists of two Fe(salen) complexes connected by the mu-(terephthalato) bridge. Each Fe atom is six coordinated by two donor atoms of the bridge and four donor atoms of the salen. Its properties are compared with those of the closely related [Fe(salen)Cl]2, [Fe(salen)]2O and [Fe(saloph)]2ter, where saloph = N,N'-o-phenylenebis(salicylaldiminato).
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页码:1579 / 1582
页数:4
相关论文
共 10 条
[1]   TWINNING BY MEROHEDRY AND X-RAY CRYSTAL-STRUCTURE DETERMINATION [J].
CATTI, M ;
FERRARIS, G .
ACTA CRYSTALLOGRAPHICA SECTION A, 1976, 32 (JAN1) :163-165
[2]   FASTER DATA-COLLECTION WITHOUT LOSS OF PRECISION - AN EXTENSION OF THE LEARNT PROFILE METHOD [J].
CLEGG, W .
ACTA CRYSTALLOGRAPHICA SECTION A, 1981, 37 (JAN) :22-28
[3]   CRYSTAL AND MOLECULAR STRUCTURE OF CHLORO-(NN'-BIS-SALICYLIDENE-ETHYLENEDIAMINE)IRON(3) AS A HEXACO-ORDINATE DIMER [J].
GERLOCH, M ;
MABBS, FE .
JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1967, (11) :1900-&
[4]   CRYSTAL AND MOLECULR STRUCTURE OF MU-OXO-BIS-[NN'-ETHYLENEBIS(SALICYLIDENEIMINATO)IRON(III)]-BISPYRIDINE [J].
GERLOCH, M ;
MCKENZIE, ED ;
TOWL, ADC .
JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1969, (18) :2850-&
[5]   ON THE ISOTROPIC TEMPERATURE FACTOR EQUIVALENT TO A GIVEN ANISOTROPIC TEMPERATURE FACTOR [J].
HAMILTON, WC .
ACTA CRYSTALLOGRAPHICA, 1959, 12 (08) :609-610
[6]   STRUCTURE OF SIGMA-(+)-5-BROMO-6,9-BIS(DIMETHYLSULPHIDO)-NIDO-DECABORANE(12), C4H23B10BRS2, DETERMINED WITH A TWINNED CRYSTAL [J].
PETRICEK, V ;
CISAROVA, I ;
SUBRTOVA, V .
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 1983, 39 (AUG) :1070-1072
[7]  
PETRICEK V, 1980, UNPUB SDS SYSTEM COM
[8]  
Shoemaker D. P., 1970, Journal of Applied Crystallography, V3, P179, DOI 10.1107/S0021889870005897
[9]  
SINDELAR Z, 1987, THESIS PALACKY U CZE
[10]   REACTION OF MU-OXO-BRIDGED IRON(III) COMPLEXES WITH ORGANIC-ACIDS - CHARACTERIZATION OF PRODUCTS [J].
WOLLMANN, RG ;
HENDRICKSON, DN .
INORGANIC CHEMISTRY, 1978, 17 (04) :926-930