RADICAL POLYMERIZATION OF DIETHYLAMINOETHYL METHACRYLATE AND ITS SALTS IN VARIOUS SOLVENTS

被引：10

作者：

BUNE, YV

SHEINKER, AP

BOGACHEV, YS

ZHURAVLEVA, IL

TELESHOV, EN

机构：

[1] Karpov Institute of Physical Chemistry, 103064 Moscow, Ul. Obukha

来源：

EUROPEAN POLYMER JOURNAL | 1991年 / 27卷 / 06期

关键词：

D O I：

10.1016/0014-3057(91)90176-O

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

NMR-spectral data for diethylaminoethyl methacrylate and its salts in various solvents have been considered with the kinetics of polymerization of these monomers. The data on the interaction of a monomer with a solvent obtained using NMR-spectroscopy lead to ideas about the effect of the formation of hydrogen bond between solvent and monomer molecules, protonization and ionization of the monomer on its reactivity in the polymerization. The effect of various conformations of growing polymer chains upon the rate of polymerization is also very important.

引用

页码：509 / 513

页数：5

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