HE(I) PHOTOELECTRON-SPECTRA OF GASEOUS ALKALI META-PHOSPHATES

被引：2

作者：

BOWLING, RA

ALLEN, JD

SCHWEITZER, GK

机构：

[1] Department of Chemistry, University of Tennessee, Knoxville

来源：

JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA | 1979年 / 17卷 / 01期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0368-2048(79)85024-0

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The He(I) photoelectron spectra of the gaseous metaphosphates of Na, K, Rb, and Cs have been obtained using a modified high-temperature cylindrical-mirror electron spectrometer equipped with a resistance-heated sample oven. Attempts to acquire data for LiPO3 have been unsuccessful because of the extremely high temperature required, of the order of 1400 K. The identities of the vapor-phase molecules were based on mass spectrometric data and the spectral lines were assigned molecular orbital origins through the use of MO calculations and analogies to other ionic compounds of similar types, particularly the alkali nitrates. © 1979.

引用

页码：25 / 32

页数：8

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